Synthesis of bio-based polyfurandicarboxylate copolymer with asymmetric substituent 2-methyl-1,3-propanediol and its thermal properties

Jie-Han Yang; Zhi-Yu Yang; Syang-Peng Rwei

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Original Research Articles · 研究論文

Synthesis of bio-based polyfurandicarboxylate copolymer with asymmetric substituent 2-methyl-1,3-propanediol and its thermal properties

合成不對稱取代基2-甲基-1,3-丙二醇之生物基聚?喃二甲酸丙烯酯共聚物及其熱性質

Jie-Han Yang 楊傑涵 ✉ National Taipei University of Technology、National Taipei University of Technology 、National Taipei University of Technology
Zhi-Yu Yang 楊智育 National Taipei University of Technology、National Taipei University of Technology 、National Taipei University of Technology
Syang-Peng Rwei 芮祥鵬 National Taipei University of Technology、National Taipei University of Technology 、National Taipei University of Technology

Abstract

Using Dimethyl 2,5-furandicarboxylate with 1,3-propanediol and 2-methyl-1,3propanediol to synthesize a series of bio-based poly(propylene 2,5-furandicarboxylate (PPF), poly(propylene-co-2-methyl-1,3-propanediol 2,5-furandicarboxylate) (PPMF) and poly(2-methyl-1,3-propylene 2,5-furandicarboxylate) (PMePF), are synthesized by conventional melt polymerization. The thermal, mechanical, and hydrophilic properties of the substituents for PPF are tested by parallax scanning thermal analyzer (DSC), thermogravimetric analyzer (TGA), dynamic mechanical analysis (DMA), and tensile testing. Increasing the content of -1,3-propanediol (MPO) will reduce the Tm and Tg of PPF, with the highest Tm and Tg of PPF, which are 175.9 ℃ and 83.0 ℃, respectively, and the enthalpy of fusion (ΔHm) is 38.6 J g-1.

Keywords

摘要

利用2,5?喃二甲酸與1,3-丙二醇及2-甲基-1,3丙二醇合成一系列生物基之聚2,5?喃二甲酸1,3-丙二醇酯(PPF)、聚2,5?喃二甲酸2-甲基-1,3丙二醇1,3-丙二醇共聚酯(PPMF)及聚2,5?喃二甲酸2-甲基-1,3丙二醇酯，通過常規之熔融聚合合成。測試取代基對於PPF的熱性能、機械性能、親水性，通過視差掃描熱分析儀(DSC)、熱重分析儀(TGA)、動態力學分析（DMA）、以及拉伸測試，隨著2-甲基-1,3-丙二醇（MPO）含量增加會降低PPF之Tm及Tg，PPF之Tm及Tg最高，分別為175.9 ℃和83.0℃熔融焓（ΔHm）為38.6 J g-1。

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Issue: Vol. 28 No. 1 (2021)
Section: Original Research Articles
Pages: 54-59
Submitted: 2021-01-15
Published: 2021-02-05
ID: JHGT-21-660
Views: 1
Downloads: 0

引用 How to cite

Yang, J. H., Yang, Z. Y., & Rwei, S. P. (2021). Synthesis of bio-based polyfurandicarboxylate copolymer with asymmetric substituent 2-methyl-1,3-propanediol and its thermal properties. Journal of the Hwa Gang Textile, 28(1), 54-59. https://jhgt.org.tw/article/view/431

@article{yang2021_431,
  author  = {Yang, Jie-Han and Yang, Zhi-Yu and Rwei, Syang-Peng},
  title   = {Synthesis of bio-based polyfurandicarboxylate copolymer with asymmetric substituent 2-methyl-1,3-propanediol and its thermal properties},
  journal = {Journal of the Hwa Gang Textile},
  year    = {2021},
  volume  = {28},
  number  = {1},
  pages   = {54--59},
  issn    = {1025-9678},
  url     = {https://jhgt.org.tw/article/view/431}
}

TY  - JOUR
AU  - Yang, Jie-Han
AU  - Yang, Zhi-Yu
AU  - Rwei, Syang-Peng
TI  - Synthesis of bio-based polyfurandicarboxylate copolymer with asymmetric substituent 2-methyl-1,3-propanediol and its thermal properties
JO  - Journal of the Hwa Gang Textile
T2  - 華岡紡織期刊
VL  - 28
IS  - 1
PY  - 2021
SP  - 54
EP  - 59
KW  - PPF
KW  - PPMeF
KW  - PPMF
KW  - biobase
KW  - Dimethyl 2
KW  - 5-furandicarboxylate
SN  - 1025-9678
UR  - https://jhgt.org.tw/article/view/431
AB  - Using Dimethyl 2,5-furandicarboxylate with 1,3-propanediol and 2-methyl-1,3propanediol to synthesize a series of bio-based poly(propylene 2,5-furandicarboxylate (PPF), poly(propylene-co-2-methyl-1,3-propanediol 2,5-furandicarboxylate) (PPMF) and poly(2-methyl-1,3-propylene 2,5-furandicarboxylate) (PMePF), are synthesized by conventional melt polymerization. The thermal, mechanical, and hydrophilic properties of the substituents for PPF are tested by parallax scanning thermal analyzer (DSC), thermogravimetric analyzer (TGA), dynamic mechanical analysis (DMA), and tensile testing. Increasing the content of -1,3-propanediol (MPO) will reduce the Tm and Tg of PPF, with the highest Tm and Tg of PPF, which are 175.9 ℃ and 83.0 ℃, respectively, and the enthalpy of fusion (ΔHm) is 38.6 J g-1.
ER  -

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