Antibacterial process of nano silver/silica/thiazole dyes hybrid materials on polyester fabrics

Chien-Wen Chen; Yang-Sheng Zeng; You-Cheng Liang; Ji-Sheng Siao; Ming-Shien Yen

Home / Archives / Vol. 24 No. 1 (2017) / Original Research Articles

Original Research Articles · 研究論文

Antibacterial process of nano silver/silica/thiazole dyes hybrid materials on polyester fabrics

奈米銀/二氧化矽與?唑染料混成材料行聚酯織物抗菌加工

Chien-Wen Chen 陳建文 Department of Materials Engineering, Kun Shan University
Yang-Sheng Zeng 曾揚升 Department of Materials Engineering, Kun Shan University
You-Cheng Liang 梁友誠 Department of Materials Engineering, Kun Shan University
Ji-Sheng Siao 蕭吉勝 Department of Materials Engineering, Kun Shan University
Ming-Shien Yen 顏明賢 ✉ Department of Materials Engineering, Kun Shan University

Abstract

A series of some novel nano silver/silica/thiazole azo dyes hybrid materials prepared via sol-gel process with vinyltriethoxysilane as precursor has been synthesized from nano silver and tetraethoxysilane with heterocyclic thiazole azo dyes. The start material thiazole was synthesized from thiourea, acetophenone derivative and iodide to get the thiazole intermediate. The 4-phenyl thiazole regards as coupling component were coupled with p-nitro aniline as diazo component at ice bath, to give the heterocyclic thiazole azo dyes. Alternatively, the heterocyclic thiazole azo dyes processed with hydrolysis-condensation reaction by the constant ratio of vinyltriethoxysilane and nano silver and tetraethoxysilane in appropriate proportion under catalyst. The surface morphology of processed PET fabrics was evaluated by scanning electron microscopy (SEM). The water contact angle, color strength, air permeability and antibacterial characteristics of the hybrid materials processed PET fabrics were subsequently evaluated.

Keywords

摘要

主要是利用溶膠-凝膠法將?唑染料、乙烯基三乙氧基矽烷、四乙氧基矽烷與奈米銀合成?唑偶氮染料之混成材料。先利用苯乙醯、硫代尿素及碘以隔水加熱迴流方式反應合成?唑中間體，將其視為偶合鹽，與對-硝基苯胺當成重氮鹽來進行偶合反應，製得?唑偶氮染料。利用一定比例的乙烯基三乙氧基矽烷與不同比例的四乙氧基矽烷及不同比例的奈米銀進行反應，製成奈米銀/二氧化矽/雜環?唑染料混成材。聚對苯二甲酸乙二酯(PET)織物進行染整加工，再藉由SEM 觀察PET加工織物其表面形貌。加工後之PET織物分析其接觸角、上色性、透氣性與抗菌性等各項物性。

關鍵字

Also in this issue

Full TOC →

A Study of the Strength of Nano-silica/Braided Composite Plates with a Central Elliptical Hole
K. H. Tsai, C. L. Hwang, C. H. Chiu, W. P. Lee, W. Y. Chen
A Study on the Fabrication of Warming Polyamide 6 Chips by Using Chemical Synthesis Method
Ruei-Wen Tsai, Chih-Ping Chin, Fu-Liang Huang, Jen-Yung Liu, Jing-Tang Chang, Kou-Bin Cheng
Effect of Application of Hydrophilic Modified Fiber on the Cool Feeling Properties of Woven Fabric
Z. S. Ciou, K. T. Kao
Microclimate Inside the Layering System
C. C. Hsu, T. H. Ku
A Study on Color Imagery of Bear Puppet Toys
Cyun-Wun Lin, Wen-Guey Kuo, Yu-Pin Li, Yi-Shan Kuo

Full text 全文

Abstract only

作者未授權開放全文下載。

Issue: Vol. 24 No. 1 (2017)
Section: Original Research Articles
Pages: 20-25
Submitted: 2016-06-29
Published: 2017-02-03
ID: JHGT-16-236
Views: 1
Downloads: 0

引用 How to cite

Chen, C. W., Zeng, Y. S., Liang, Y. C., Siao, J. S., & Yen, M. S. (2017). Antibacterial process of nano silver/silica/thiazole dyes hybrid materials on polyester fabrics. Journal of the Hwa Gang Textile, 24(1), 20-25. https://jhgt.org.tw/article/view/253

@article{chen2017_253,
  author  = {Chen, Chien-Wen and Zeng, Yang-Sheng and Liang, You-Cheng and Siao, Ji-Sheng and Yen, Ming-Shien},
  title   = {Antibacterial process of nano silver/silica/thiazole dyes hybrid materials on polyester fabrics},
  journal = {Journal of the Hwa Gang Textile},
  year    = {2017},
  volume  = {24},
  number  = {1},
  pages   = {20--25},
  issn    = {1025-9678},
  url     = {https://jhgt.org.tw/article/view/253}
}

TY  - JOUR
AU  - Chen, Chien-Wen
AU  - Zeng, Yang-Sheng
AU  - Liang, You-Cheng
AU  - Siao, Ji-Sheng
AU  - Yen, Ming-Shien
TI  - Antibacterial process of nano silver/silica/thiazole dyes hybrid materials on polyester fabrics
JO  - Journal of the Hwa Gang Textile
T2  - 華岡紡織期刊
VL  - 24
IS  - 1
PY  - 2017
SP  - 20
EP  - 25
KW  - nano silver
KW  - hybrid materials
KW  - PET fabrics
KW  - antibacterial
KW  - contact angle
SN  - 1025-9678
UR  - https://jhgt.org.tw/article/view/253
AB  - A series of some novel nano silver/silica/thiazole azo dyes hybrid materials prepared via sol-gel process with vinyltriethoxysilane as precursor has been synthesized from nano silver and tetraethoxysilane with heterocyclic thiazole azo dyes. The start material thiazole was synthesized from thiourea, acetophenone derivative and iodide to get the thiazole intermediate. The 4-phenyl thiazole regards as coupling component were coupled with p-nitro aniline as diazo component at ice bath, to give the heterocyclic thiazole azo dyes. Alternatively, the heterocyclic thiazole azo dyes processed with hydrolysis-condensation reaction by the constant ratio of vinyltriethoxysilane and nano silver and tetraethoxysilane in appropriate proportion under catalyst. The surface morphology of processed PET fabrics was evaluated by scanning electron microscopy (SEM). The water contact angle, color strength, air permeability and antibacterial characteristics of the hybrid materials processed PET fabrics were subsequently evaluated.
ER  -

下載 .ris 下載 .bib

分享 Share